ASTM D5623-1994(2004)e1 用气相色谱法和硫化选择性检测法测定轻质石油液体中硫化物的试验方法
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【英文标准名称】:StandardTestMethodforSulfurCompoundsinLightPetroleumLiquidsbyGasChromatographyandSulfurSelectiveDetection
【原文标准名称】:用气相色谱法和硫化选择性检测法测定轻质石油液体中硫化物的试验方法
【标准号】:ASTMD5623-1994(2004)e1
【标准状态】:现行
【国别】:
【发布日期】:1994
【实施或试行日期】:
【发布单位】:美国材料与试验协会(US-ASTM)
【起草单位】:D02.04
【标准类型】:(TestMethod)
【标准水平】:()
【中文主题词】:燃料;石油产品;化学分析和试验;硫含量;试验方法;试验;液体燃料
【英文主题词】:atomicemissiondetection;gaschromatography;sulfurchemiluminescencedetection;sulfurcompounds
【摘要】:Gaschromatographywithsulfurselectivedetectionprovidesarapidmeanstoidentifyandquantifysulfurcompoundsinvariouspetroleumfeedsandproducts.Oftenthesematerialscontainvaryingamountsandtypesofsulfurcompounds.Manysulfurcompoundsareodorous,corrosivetoequipment,andinhibitordestroycatalystsemployedindownstreamprocessing.Theabilitytospeciatesulfurcompoundsinvariouspetroleumliquidsisusefulincontrollingsulfurcompoundsinfinishedproductsandisfrequentlymoreimportantthanknowledgeofthetotalsulfurcontentalone.1.1Thistestmethodcoversthedeterminationofvolatilesulfur-containingcompoundsinlightpetroleumliquids.Thistestmethodisapplicabletodistillates,gasolinemotorfuels(includingthosecontainingoxygenates)andotherpetroleumliquidswithafinalboilingpointofapproximately230176;C(450176;F)orloweratatmosphericpressure.Theapplicableconcentrationrangewillvarytosomeextentdependingonthenatureofthesampleandtheinstrumentationused;however,inmostcases,thetestmethodisapplicabletothedeterminationofindividualsulfurspeciesatlevelsof0.1to100mg/kg.1.2Thetestmethoddoesnotpurporttoidentifyallindividualsulfurcomponents.Detectorresponsetosulfurislinearandessentiallyequimolarforallsulfurcompoundswithinthescope(1.1)ofthistestmethod;thusbothunidentifiedandknownindividualcompoundsaredetermined.However,manysulfurcompounds,forexample,hydrogensulfideandmercaptans,arereactiveandtheirconcentrationinsamplesmaychangeduringsamplingandanalysis.Coincidently,thetotalsulfurcontentofsamplesisestimatedfromthesumoftheindividualcompoundsdetermined;however,thistestmethodisnotthepreferredmethodfordeterminationoftotalsulfur.1.3ThevaluesstatedinSIunitsaretoberegardedasthestandard.Thevaluesgiveninparenthesesareforinformationonly.1.4Thisstandarddoesnotpurporttoaddressallofthesafetyconcerns,ifany,associatedwithitsuse.Itistheresponsibilityoftheuserofthisstandardtoestablishappropriatesafetyandhealthpracticesanddeterminetheapplicabilityofregulatorylimitationspriortouse.
【中国标准分类号】:E30
【国际标准分类号】:75_160_20
【页数】:6P.;A4
【正文语种】:
【原文标准名称】:用气相色谱法和硫化选择性检测法测定轻质石油液体中硫化物的试验方法
【标准号】:ASTMD5623-1994(2004)e1
【标准状态】:现行
【国别】:
【发布日期】:1994
【实施或试行日期】:
【发布单位】:美国材料与试验协会(US-ASTM)
【起草单位】:D02.04
【标准类型】:(TestMethod)
【标准水平】:()
【中文主题词】:燃料;石油产品;化学分析和试验;硫含量;试验方法;试验;液体燃料
【英文主题词】:atomicemissiondetection;gaschromatography;sulfurchemiluminescencedetection;sulfurcompounds
【摘要】:Gaschromatographywithsulfurselectivedetectionprovidesarapidmeanstoidentifyandquantifysulfurcompoundsinvariouspetroleumfeedsandproducts.Oftenthesematerialscontainvaryingamountsandtypesofsulfurcompounds.Manysulfurcompoundsareodorous,corrosivetoequipment,andinhibitordestroycatalystsemployedindownstreamprocessing.Theabilitytospeciatesulfurcompoundsinvariouspetroleumliquidsisusefulincontrollingsulfurcompoundsinfinishedproductsandisfrequentlymoreimportantthanknowledgeofthetotalsulfurcontentalone.1.1Thistestmethodcoversthedeterminationofvolatilesulfur-containingcompoundsinlightpetroleumliquids.Thistestmethodisapplicabletodistillates,gasolinemotorfuels(includingthosecontainingoxygenates)andotherpetroleumliquidswithafinalboilingpointofapproximately230176;C(450176;F)orloweratatmosphericpressure.Theapplicableconcentrationrangewillvarytosomeextentdependingonthenatureofthesampleandtheinstrumentationused;however,inmostcases,thetestmethodisapplicabletothedeterminationofindividualsulfurspeciesatlevelsof0.1to100mg/kg.1.2Thetestmethoddoesnotpurporttoidentifyallindividualsulfurcomponents.Detectorresponsetosulfurislinearandessentiallyequimolarforallsulfurcompoundswithinthescope(1.1)ofthistestmethod;thusbothunidentifiedandknownindividualcompoundsaredetermined.However,manysulfurcompounds,forexample,hydrogensulfideandmercaptans,arereactiveandtheirconcentrationinsamplesmaychangeduringsamplingandanalysis.Coincidently,thetotalsulfurcontentofsamplesisestimatedfromthesumoftheindividualcompoundsdetermined;however,thistestmethodisnotthepreferredmethodfordeterminationoftotalsulfur.1.3ThevaluesstatedinSIunitsaretoberegardedasthestandard.Thevaluesgiveninparenthesesareforinformationonly.1.4Thisstandarddoesnotpurporttoaddressallofthesafetyconcerns,ifany,associatedwithitsuse.Itistheresponsibilityoftheuserofthisstandardtoestablishappropriatesafetyandhealthpracticesanddeterminetheapplicabilityofregulatorylimitationspriortouse.
【中国标准分类号】:E30
【国际标准分类号】:75_160_20
【页数】:6P.;A4
【正文语种】:
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